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Acetone and polystyrene foam

Submitted by sat on 02 May 2019

Suitability for primary schools:

There are two aspects to consider here:

  1. The curriculum application. This is a complex example of a physical change and not easily reversible. Simple examples of a physical change1 are recommended for the primary school level, such as
    1. change of state (e.g. from a solid to a liquid or gas or the reverse)
    2. creation and/or separation of a mixture (e.g. mixing sand with marbles)
    3. physical deformation (e.g. crumpling or tearing paper)
  2. Management of hazardous chemicals in primary schools: Are there systems in place to ensure that the risks to health and safety are managed? For example: Has a chemical register for hazardous chemicals been established and maintained? Has appropriate information and training been provided for staff? 2

Handling acetone

Acetone is a hazardous chemical. It is highly flammable, in both liquid and vapour form; it causes serious eye irritation and may cause drowsiness or dizziness.3

Safe storage and handling procedures must be followed:

Acetone and polystyrene foam demonstration

Polystyrene is a polymer made up of the monomer styrene5. It is a hard, solid plastic used in many appliances.6 When polystyrene beads contain an expanding agent and are steam heated, they soften and expand up to forty times their original size to form polystyrene foam which is 98% air.7

The Royal Society of Chemistry explains that when polystyrene foam comes into contact with acetone, it is softened and releases the air and therefore collapses.  “The resulting colloidal gel consists of propanone (acetone) molecules dispersed in a network formed by a tangle of large polystyrene molecules – a similar structure to ordinary jelly in which water molecules are dispersed in a network of protein molecules.8

This means that this is a physical change because there has been no chemical change to the polystyrene.9 Since it is largely air that is released, there is unlikely to be exposure to toxic gases from this source. The greatest risks in this activity are exposure to the acetone and its flammability.

Science ASSIST recommends that this activity is conducted as a demonstration rather than a class activity, observing the following:

References

1 ‘3.6: Changes in Matter - Physical and Chemical Changes’, Chemistry Libre text library website, hyperlink (Updated May 2019) 

2 ‘Hazardous chemicals’, Safe work Australia website, https://www.safeworkaustralia.gov.au/chemicals (Accessed April 2019)

3 Chem Supply. 2015. Acetone, Safety Data Sheet, Chem Supply website,  https://www.chemsupply.com.au/documents/AA0081CH01.pdf

4 Science ASSIST. 2017. Handbook Chemical Management Handbook for Australian Schools – Edition 3 https://assist.asta.edu.au/resource/4193/chemical-management-handbook-australian-schools-edition-3

5 ‘What Makes Polystyrene Different from Styrene? It’s a Matter of Chemistry’, Chemical Safety Facts website, https://www.chemicalsafetyfacts.org/chemistry-context/makes-polystyrene-different-styrene-matter-chemistry/  (Accessed April 2019)

6 ‘Polystyrene’, Chemical Safety Facts website, https://www.chemicalsafetyfacts.org/polystyrene/ (Accessed April 2019)

7 Bellis, Mary. 2019. ‘Invention of Polystyrene and Styrofoam’ ThoughtCo. website, https://www.thoughtco.com/invention-of-polystyrene-and-styrofoam-1992332 (24 January 2019)

8 ‘Disappearing plastic’, Royal Society of Chemistry Learn Chemistry website, http://rsc.org/learn-chemistry/resource/res00001721/disappearing-plastic (July 2016)

9 Helmenstine, Anne Marie. 2018. ‘Physical Changes in Chemistry’, ThoughtCo. website, https://www.thoughtco.com/definition-of-physical-change-605910 (11 April 2018)