Storage of nitrates

Storage of nitrates: Hi, I'm upgrading the storage of my chemicals. Is it okay to store nitrates in clear glass bottles?

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Publication Date: 01 March 2016
Asked By: tkirk
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storage of nitrates

In brief


Where possible, it is recommended to keep chemicals in the original container in which the chemical was supplied1. If it is necessary to transfer to a new container, Science ASSIST recommends that you consult the relevant SDS for each nitrate that you wish to transfer to confirm specific storage instructions. Clear glass bottles are not the best option for the storage of light-sensitive chemicals, such as many of the nitrates. We suggest amber glass or opaque high-density polyethylene (HDPE) jars as the best alternatives.


The AS/NZS 2243.10:2004 Storage of chemicals states:


Section 7 Package opening and transfer


7.3 Transferring and repackaging


‘Where an empty container is to be filled with a chemical for storage and use at another time, it –


  1. Shall be suitable for the product, particularly in relation to its compatibility with the intended contents and the vapour pressure that can be generated’2


The following aspects should be taken into consideration regarding the storage of, and storage containers for, nitrates.


  • Chemical incompatibilities: Most nitrates are classed as oxidisers and should be stored away from organic compounds, flammable or combustible materials and reducing agents.
  • Many nitrates are light sensitive. The nitrate ion can be photolysed on exposure to UV light.3 This process is indicated by the formation of a yellow colour in the solid nitrate.3 The product/s of photolysis can decompose further to form the more toxic nitrite ion, when dissolved in water.3 It is therefore important to protect these substances from sunlight. They are best stored in the original container or in an amber glass or compatible opaque plastic container; clear glass bottles are not suitable.
  • Many nitrates are hygroscopic, which means that they absorb water from the air. Therefore, it is important to ensure that containers have a good seal and are stored in cool, dry locations. It is often advised to store the chemical in its container within a desiccator.
  • Nitrates are often supplied in plastic jars. High-density polyethylene (HDPE) is compatible with nitrates, however many other plastics are not.
  • Decanting nitrates from the original container: It is important that nitrates are not stored in contact with any incompatible substances (flammable or combustible substances or reducing agents). If the storage containers into which the nitrate is to be decanted are not new, ensure that the containers and their lids are not contaminated with any of these substances.

Additional information


In a laboratory, there are a variety of containers available for the storage of chemicals. It is important that the container chosen is in sound condition and is compatible with the chemical being stored.1 Choosing the incorrect container can lead to a chemical’s deterioration, the escape of hazardous fumes, or a build-up of pressure. Knowing the physical and chemical properties of a chemical is important in determining the best type of storage container. Therefore, before using any chemical, it is recommended to consult its safety data sheet and chemical label for specific storage instructions. It is also important to regularly check that the existing containers are still in good condition.


Selection of suitable containers for the storage of chemicals


  • Chemical containers can be made from glass or particular plastics.
    • Glass containers are generally chemically inert, some types are recyclable, and some are available with an amber tint for light-sensitive chemicals.
    • Plastic containers are more lightweight and not easily breakable. They are available in clear, translucent or opaque. A chemical compatibility chart needs to be consulted for the compatibility of chemicals with different types of plastics. Some plastics may degrade after extended contact with a particular chemical or may become brittle with exposure to sunlight.
  • The chemical needs to be compatible with the container material and its lid.
  • Ensure that containers are in good condition and leak proof.
  • Where possible, keep to the original container that the chemical was supplied in.1
  • Never use a food or household container to store a chemical.1
  • Light-sensitive chemicals should be stored in opaque or amber-coloured containers to protect from visible and UV radiation. Clear glass bottles/jars are not suitable for these chemicals.
  • Solid chemicals and powders are best stored in wide-mouthed jars with screw caps so that the contents can be easily accessed and removed with a spatula.
  • Liquid chemicals are best stored in narrow-mouthed bottles so they can be easily dispensed or poured. Some bottles are fitted with pouring rings to assist in this process.
  • If decanting into another container:
    • select a container of the same material as the original container, or ensure the container is compatible with the chemical;
    • ensure that the labelling is current;
    • ensure that the lid used fits so that vapours are contained and spills prevented.
  • The type of lid must also be compatible with the chemical being stored, for example:
  • ground glass stoppers are not recommended for storing alkali solutions such as aqueous sodium hydroxide. Hydroxide solution can react with the glass, causing the ground-glass joints to freeze;
  • if chemicals have the potential to decompose with the generation of gases, such as with hydrogen peroxide, the container should have a vented lid.

References


1 Queensland Department of Education, Training and Employment, Organisational Health. 2013. Guideline for Managing Risks with Chemicals in DETE Workplaces, p 24,


http://education.qld.gov.au/health/pdfs/healthsafety/guideline-managing-chemicals.pdf


2 Standards Australia. 2004. AS/NZS 2243 Safety in Laboratories, Part 10: 2004 Storage of chemicals. Sydney, Australia. This extract has been reproduced with permission from SAI Global Ltd under Licence 1407-c117.


3 Plumb, R. C., Edwards, J. O., ‘Color centers in UV-irradiated nitrates’. Journal of Physical Chemistry, 96, (1992), p 3245.


‘Ammonium nitrate’, Safety Data Sheet, Sigma website, http://www.sigmaaldrich.com/MSDS/MSDS/DisplayMSDSPage.do?country=AU&lang... (November 2013)


Burkle GmbH. ‘List of chemical resistance and viscosity 2015’ , Burkle website, https://www.buerkle.de/files_pdf/wissenswertes/chemical_resistance_en_20... (Accessed October 2016)


‘Nitrates and nitrites’, IPCS INCHEM website, http://www.inchem.org/documents/pims/chemical/pimg016.htm (Accessed March 2016)


‘Plastic bottle’, Wikipedia website, https://en.wikipedia.org/wiki/Plastic_bottle (Accessed March 2016)


‘Plastic Container Styles’, Qorpak website, http://www.qorpak.com/pages/ContainersandClosuresPlasticStyles (Accessed March 2016)


‘Reagent bottle’ Wikipedia website, https://en.wikipedia.org/wiki/Reagent_bottle (Accessed March 2016)


‘Safety Fact sheet – oxidisers’ Nangyang Technological University, School of Physical and Mathematical Sciences website. https://web.archive.org/web/20160222031526/http://www.spms.ntu.edu.sg/cb... (Link no longer exists, this copy made available by the Internet Archive's Wayback Machine (August, 2017).


‘Silver nitrate’, Material Safety Data Sheet, Chem-supply website, https://www.chemsupply.com.au/documents/SL0871CH63.pdf (September 2011)


‘Sodium nitrate’, Safety Data Sheet, Sigma website, http://www.sigmaaldrich.com/MSDS/MSDS/DisplayMSDSPage.do?country=AU&lang... (December 2014)

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